Image with no alt text. Image with no alt text. Oblix. Related Collections. WSService.On the mechanism of the temperature-induced self-assembly of binary mixtures of amphiphilic block copolymer thin films.
The temperature-induced self-assembly of binary mixtures of poly(ethylene glycol)-block-polycaprolactone (PEG-b-PCL) and poly(ethylene glycol)-block-poly(2-methacryloyloxyethyl phosphorylcholine) (PEG-b-PMPC) thin films is studied by dielectric spectroscopy. The simultaneous measurement of complex permittivity and conductivity allows to study the electrophoretic mobility of the film as a function of temperature. The present analysis, based on thermodynamic considerations, highlights the existence of a critical point in the binary phase diagram. The same mechanism, based on small energetic variations, leads to the same conclusion in the temperature-induced self-assembly of the binary mixtures of PEG-b-PCL and PEG-b-PMEA thin films.The Stethoscope Of God
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